节点文献
矩阵投影算法用于校正ICP-AES中的光谱干扰
CORRECTION OF SPECTRAL INTERFERENCES IN INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY WITH A MODIFIED CHEMOMETRIC METHOD BASED ON MATRIX PROJECTION
【摘要】 本文将矩阵投影算法应用于ICP-AES中光谱干扰的校正。在有关文献方法基础上,对残差作了进一步的校正,并采用最优化技术确定背景光谱的最优解,因而提高了方法的准确度。对实际干扰体系的校正结果表明,本方法能够对ICP-AES中比较复杂的结构背景以及谱线重叠干扰进行较为准确地校正。
【Abstract】 A modified chemometric method based on matrix projection was developed to correct the spectral interferences in inductively coupled plasma atomic emission spectrometry(ICP AES).The accuracy of the correction was significantly improved by reevaluating the residuals.The excellent analytical results for some rare earth elements proved the method fairly feasible.
【关键词】 矩阵投影算法;
ICP-AES;
光谱干扰校正;
【Key words】 Matrix projection; ICP AES; Correction of spectral interference;
【Key words】 Matrix projection; ICP AES; Correction of spectral interference;
【基金】 国家自然科学基金,国家教委博士点基金
- 【文献出处】 光谱学与光谱分析 ,SPECTROSCOPY AND SPECTRAL ANALYSIS , 编辑部邮箱 ,1998年02期
- 【分类号】TH838.2,
- 【被引频次】10
- 【下载频次】78