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富勒烯化聚环氧丙基咔唑的合成与表征

Preparation and Characterization of Fullerenated Poly(epoxy propyl carbazole)

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【作者】 顾涛陈万喜徐铸德

【Author】 Gu Tao * Chen Wanxi Xu Zhude (Department of Chemistry, Zhejiang University, Hangzhou 310027)

【机构】 浙江大学化学系

【摘要】 通过Friedel-Crafts反应制备了富勒烯化的聚环氧丙基咔唑,聚合物中C60的含量最高可达7.6wt%。通过凝胶渗透色谱法测定了聚合物分子量,并采用1H和13CNMR,IR,热分析及光谱等手段对其结构进行了分析与表征。

【Abstract】 The fullerenated PEPC[Poly(epoxy propyl carbazole)] was synthesized by Friedel-Crafts type reactions. Molecular weights of the polymers were determined by gel permeation chromatography. Structures of the polymers were analyzed and characterized by use of proton and 13 C-NMR, IR, thermal analysis and optical spectroscopic methods. The 13 C-NMR spectrum of the fullerenated PEPC exhibits signal in the fullerene region. Compared with pure PEPC, the fullerenated PEPC has the same structure in UV region of the absorption spectrum and extends the active range to longer wavelength. The quenching of PEPC fluorescence was observed in the fullerenated polymer and it can be attributed to intramolecular excited state energy transfer. The fullerenated PEPC is soluble in common organic solvents such as THF and chloroform. The process can be generalized to other polymers having phenyl groups to produce a series of fullerenated polymers.

【基金】 国家自然科学基金,国家教委博士点基金,浙江省自然科学基金
  • 【文献出处】 功能高分子学报 ,JOURNAL OF FUNCTIONAL POLYMERS , 编辑部邮箱 ,1998年04期
  • 【分类号】O63
  • 【被引频次】4
  • 【下载频次】70
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