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手性2-苯基嘧啶类液晶的合成研究

Synthesis and Properties of Chiral 2Phenylpyrimidine Liquid Crystalline Compounds

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【作者】 商永嘉陆婉芳陆友梅丁晖

【Author】 Shang Yongjia Lu Wanfang Lu Youmei Din Hui(Department of Chemistry,Nanjing University, Nanjing,210093,China)

【机构】 南京大学化学化工学院

【摘要】 合成了4个系列共20个手性双烷氧基端基2-苯基嘧啶化合物,其中13个是新化合物。液晶性质测试结果表明它们都是近晶相液晶,有些还有多相性。文中讨论了不同端基对液晶性质的影响。

【Abstract】 Four series ⅠⅣ,total 20 compounds of chiral 2phenylpyrimidine with two alkyloxy terminal groups were synthesized. Among them,13 compounds were new compounds. The chemical structures of all compounds were determined by IR,1HNMR, MS and elementary analysis. Their liquid crystal properties were tested by POM and DSC. The results showed that they all had a smectic phase and some of them had a chiral smectic C phase (Sc*) near room temperature. The effect of different terminal groups on the mesomorphic properties was discussed.

【基金】 江苏省科委资助项目
  • 【文献出处】 功能材料 ,JOURNAL OF FUNCTIONAL MATERIALS , 编辑部邮箱 ,1998年04期
  • 【分类号】TQ25
  • 【被引频次】3
  • 【下载频次】114
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