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广西煤的X射线衍射特征

X-RAY DIFFRACTION PATTERNS OF COALS IN GUANGXI

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【作者】 陈儒庆曹长春阮贵华

【Author】 Chen Ruqing Cao Changchun Ruan Guihua (Guilin Institute of Technology)

【机构】 桂林工学院资源与环境工程系

【摘要】 系统分析了广西未变质煤、区域变质煤、岩浆变质煤和热液变质煤的X射线衍射特征。随煤变质程度升高,(002)衍射峰的衍射角增大、半高宽缩小、芳环层面网间距缩小;(10l)衍射峰从无到有、半高宽缩小;第Ⅲ衍射峰仅在无烟煤中出现。对烟煤而言,其有序化程度的升高主要取决于煤中稠合度小的有机化合物的脱落;对无烟煤而言,其有序化程度的升高则取决于热液作用的次数和时间的长短。

【Abstract】 The X-ray diffraction patterns of unmetamorphosed,regionally metamorphosed, thermally metamorphosed and hydrothermally metamorphosed coals have been systematically analysed. For the (002) diffraction peak, the diffraction angle will increase, but the half-height width and the spacing of the plane net of aromatic ring layer will decrease with a gradual increase on coal rank. The (10l) diffraction peak will gradually appear and its half-width will decrease as the coal rank increases. The third diffraction peak, appearing when 2θ≈80°, only exists in anthracites. The ordering degree of bituminous coal will increase as the low-consistency organic compound in coal comes off. However, the ordering degree of anthracites is in direct proportion to the frequent and longterm hydrothermal process.

【关键词】 X射线衍射化学结构广西
【Key words】 coalX-ray diffractionchemical constructionGuangxi
【基金】 国家自然科学基金,广西壮族自治区科学研究与技术开发项目
  • 【文献出处】 桂林工学院学报 ,JOURNAL OF GUILIN INSTITUTE OF TECHNOLOGY , 编辑部邮箱 ,1998年01期
  • 【分类号】P575.5,P618.110.4
  • 【被引频次】1
  • 【下载频次】176
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