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N-己基异辛酰胺萃取铑和铱

Extraction of Rhodium(Ⅲ) and Iridium(Ⅳ) by N-hexyl isooctylamide

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【作者】 董正卿古国榜程飞魏小兰

【Author】 Dong Zhengqing, Gu Guobang, Cheng Fei, Wei Xiaolan (Department of Applied Chemistry, South China University of Technology, Guang Zhou 510641,China)

【机构】 华南理工大学应用化学系

【摘要】 以N-己基异辛酰胺作为Ir(Ⅳ)的新型萃取剂用于Rh、Ir分离,考察不同稀释剂的分相情况,有机相组成对萃取率的影响。选择TBP-正辛烷作有机相稀释剂,考察水相介质中H+、Cl-浓度以及Cu2+、Fe3+、Ni2+的萃取行为。结果认为水是最有效的反萃剂

【Abstract】 N-hexyl isooctylamide was used as an extractant of Ir(Ⅳ)for separation from Rh. The influence of thinner on phase separation and of components in organic phase on the extraction has been investigated. Under selecting TBP-octane as a thinner, the influence of H +, Cl - ions concentration in aqueous medium on the extraction, and extractive behaviour of Cu 2+ ,Fe 3+ ,Ni 2+ ions have been investigated. The water was the most efficient stripping agent.

【关键词】 N-己基异辛酰胺溶剂萃取
【Key words】 IridiumRhodiumN-hexyl isooctylamideSolvent extraction
  • 【分类号】O652.62
  • 【被引频次】7
  • 【下载频次】132
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