【摘要】 梯形聚合物ＢＢＬ－［ｐｏｌｙ（ｂｅｎｚｉｍｉｄａｚｏｂｅｎｚｏｐｈｅｎａｎｔｈｒｏｌｉｎｅ）ｌａｄｄｅｒｐｏｌｙｍｅｒ］由１，２，４，５－四胺苯和１，４，５，８－萘四羧酸合成。基体物上的ＢＢＬ膜由投放ＢＢＬ的ＡｌＣｌ３／硝基甲烷溶液制备。ＢＢＬ膜注入Ｐ＋和Ｂ＋离子后，可观察到其电导和谱特征（红外、紫外－可见光和顺磁共振谱）的变化。用氯化碘掺杂的ＢＢＬ膜也进行了对照研究。更多还原

【Abstract】 Ladder polymer poly(benzimidazobenzophenanthroline)(BBL) was synthesized from 1,2,4,5tetraaminobenzene and 1,4,5,8naphthalenetetracarboxylic acid. BBL films supported on substrates were produced by casting AlCl3/nitromethane solution of BBL. The BBL films were doped with P+ and B+ by ion implantation. The changes of spectroscopic characteristics(IR, UVvisible and ESR) and conductivity were observed. The BBL film doped by ICl was also studied as a contrast.更多还原