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阳离子型温敏水凝胶的合成与性质

SYNTHESIS AND PROPERTIES OF THERMOSENSITIVE CATIONIC HYDROGELS

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【作者】 王昌华卢英先曹维孝

【Author】 WANG Changhua,\ LU Yingxian,\ CAO Weixiao(The College of Chemistry and Molecular Engineering, Peking University, Beijing 100871)

【机构】 北京大学化学与分子工程学院

【摘要】 阳离子型温敏水凝胶的合成与性质王昌华卢英先曹维孝(北京大学化学与分子工程学院北京100871)关键词热缩温敏水凝胶,N异丙基丙烯酰胺,N乙烯基吡啶氟硼酸盐,N甲基4乙烯基吡啶硫酸甲酯盐水凝胶可看作是水溶或亲水高分子的一种亲水网络.多数...

【Abstract】 The thermosensitive hydrogels were prepared from the copolymerization of N-Isopropyl-acrylamide and N-vinyl pyridium tetrafluroborate(NVP.BF4) or N-methyl-4- vinyl pyridium methylsulfate (NMVP.CH3SO4) as cationic comonomers in the presence of methylene bisacrylamide(MBA) as crosslinking agent by means of γ-r and crosslinking agent on the properties of hydrogel especially the swelling ratio(SR) and sensitive temperature have been investigated The results show that the SR of the hydrogels will increase with the increasing the content of cationic monomer or decreasing the content of crosslinking agent. The sensitive temperature of the hydrogel will also increase with increasing the content of the cationic monomer but the content of the crossing agent seems to have no influence on it.

【基金】 国家自然科学基金
  • 【文献出处】 高分子学报 ,ACTA POLYMERICA SINICA , 编辑部邮箱 ,1998年02期
  • 【分类号】TQ326.4
  • 【被引频次】41
  • 【下载频次】412
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