节点文献
马来酸酐接枝聚丙烯的等温结晶动力学研究
KINETICS OF ISOTHERMAL CRYSTALLIZATION FOR MALEIC ANHYDRIDE GRAFT POLYPROPYLENE
【摘要】 用DSC法追踪了马来酸酐接枝聚丙烯的等温结晶过程,讨论了马来酸酐降低聚丙烯球晶径向生长自由能,提高结晶速率,但降低聚丙烯结晶度的物理和化学机制.同时探讨了马来酸酐的接枝对球晶生长和成核机制的影响.
【Abstract】 The samples of maleic anhydride graft polyproylene conposing different quantity of maleic anhydride are prepared.The kinetics of isothermal crystallization has been investigated by DSC.The physical and chemical mechanism by which succinic anhydride group reduces the surface free energy of radial growth of PP spherulite,increases the crystallization rate,but reduces the crystallinity was demonstrated.The influence of succinic anhydride group on mechanism of spherulite growth and nucleation was discussed.
【关键词】 聚丙烯;
马来酸酐;
接枝反应;
等温结晶;
结晶度;
球晶生长;
成核机理;
表面自由能;
【Key words】 Polypropylene; Maleic anhydride; Graft polymerization; Isothermal crystallization; Spherulite growth; Surface free energy; Nucleation;
【Key words】 Polypropylene; Maleic anhydride; Graft polymerization; Isothermal crystallization; Spherulite growth; Surface free energy; Nucleation;
- 【文献出处】 高分子学报 ,ACTA POLYMERICA SINICA , 编辑部邮箱 ,1998年01期
- 【分类号】O632
- 【被引频次】41
- 【下载频次】370