【摘要】 前文［１，２］报道了二级化学键存在于若干金属有机化合物以及某些簇合物中，实际上，在Ｆｉｇ．１ＣｒｙｓｔａｌｓｔｒｕｃｔｕｒｅｏｆＣｕＬ２［１４］┐２ｑｕ某些配合物体系中亦存在着二级化学键．本文将着重研究喹啉基氮杂环铜配合物（ＣｕＬ２［１４］－２ｑｕ）...更多还原

【Abstract】 According to the data of X ray crystal structure of CuL 2 2qu, we have used the calculating methods of molecular mechanics, quantum chemistry CNDO/2 and molecular electrostatic potential. The results show that there are the secondary chemical bonds between Cu(Ⅱ) and N of quinoline ring in the coordinate compound(CuL 2 2qu). The existance of secondary chemical bonnds makes the two quinoline pendants on the different sides of the macrocycle plane and the three atoms N11—Cu—N12 nearly co linear.更多还原