【摘要】 首次报道了一个新的拟酶模型物双［Ｎ，Ｎ－１，２－亚乙基－２，２－（苯基亚甲基）二（３，４－二甲基吡咯－５－醛缩亚胺）］合双锰的合成方法及光谱特征；并对用ＰｈＩＯ单加氧化环己烷反应的催化性能及自氧化反应进行了研究．结果表明，此Ｓｃｈｉｆ碱双锰配合物的催化性能及稳定性与金属卟啉ＴＰＰＭｎＣｌ相似．更多还原

【Abstract】 This paper first reports the synthesis and spectral characterization of bis N,N  ethylene 2,2 (phenylmethylene)bis(3,4 dimethylpyrrole 5 aldimino) dimanganese as well as the biomimetic catalytic properties for the monooxygenation of cyclohexane with PhIO. The results show that the catalytic properties and stability of this binuclear manganese complex are similar to those of TPPMnCl and better than those of other Schiff base complexes known.更多还原