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利用碘-三辛胺盐酸盐反应分光光度测定TOA·HCl

Determination of Trioctylamine Salt by Spectrophotometric Iodine Method

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【作者】 沈纬; 罗世忠; 胡旭风; 付洵;

【Author】 Shen Wei, Luo Shizhong, Hu Xufeng, Fu Xun (Department of Applied Chemistry,Qingdao Institute of Chemical Technology, Qingdao, 266042)

【机构】 青岛化工学院应用化学系;

【摘要】 研究了测定三辛胺盐酸盐(简称TOA·HCl)的一种新方法——碘光谱法.TOA·HCl在四氯化碳溶液中与碘生成电荷转移化合物,该物质的最大吸收波长为370nm.TOA·HCl在0~4×10-4mol·L-1范围内符合比耳定律.该方法准确、简便、快速,其它溶剂的干扰较小,回收率在94.5%~101.9%,能够满足分析的需要.

【Abstract】 A new method for determination Tri n octylamine salt (TOA·HCl) by spectro photometric iodine method has been studied in this paper.TOA·HCl reacted with Iodine in the solution of CCl 4 to produce electron transfer complex.The maximum absorbance of the complex was at 370nm.Beer’s law was obeyed in the range of 0 ̄4×10 -4 mol·L -1 for TOA·HCl. The method was sensitive, simple, rapid and the interference of the other solvents was little.The recoveries were between 94.4% ̄101.9%. It can satisfy the requirement of analysis perfectly.

  • 【文献出处】 分析科学学报 ,JOURNAL OF ANALYTICAL SCIENCE , 编辑部邮箱 ,1998年04期
  • 【分类号】O657.32
  • 【被引频次】1
  • 【下载频次】92
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