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K比例H点标准加入法计算研究

K -Ratio H -Point Standard Addition Method and Its Application

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【作者】 刘国民赵杉林王黎沈春玉孙树江

【Author】 Liu Guomin, Zhao Shanlin, Wang Li, Shen Chunyu, Sun Shujiang (Department of Applied Chemistry, Fushun Petroleum Institute, Fushun 113001)

【机构】 抚顺石油学院应用化学系!抚顺113001

【摘要】 为了获得在有干扰存在下的复杂体系中待测样品的准确浓度,提出了称为“K比例H点标准加入法”的方法。此方法通过在选定的两波长下样品标准加入浓度与吸光度的线性方程经K比例法消除干扰后求出其交点H(- CH,AH),则CH就是待测物的浓度。本文研究了这种方法的回归及H点计算的方法并给出了应用程序实例。

【Abstract】 A method, called "K-Ratio H-Point Standar Addition Method", was proposed. At two different wavelengths, a K ratio was introduced to the regression equations of the absorbance against the concentrations of standard addition of the analytes to eliminate the interference, after calculating, the intersection, H-point (coordinte at (- CH, AH) ), of the two regrssion lines was obtained. Then the CH is the concentration of the analyte. In this paper, the application of this method to the determination of salicylic acid in its mixture is described.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1998年09期
  • 【分类号】O652.9
  • 【被引频次】10
  • 【下载频次】90
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