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12种嘌呤类化合物的滤纸基质室温燐光法研究
Solid Surface Room Temperature Phosphorescence of Twelve Purine Derivatives
【摘要】 较为详细地研究了12种嘌呤类化合物以滤纸为基质的室温燐光(RTP)光谱特性与分子结构的关系,以及重原子效应和酸度效应对RTP的影响。
【Abstract】 The solid surface room temperature phosphorescence (SS-RTP) of twelve purine derivatives using China-made filter paper as solid substrate was given. The relation between molecular structure and spetrum, the effects of heavy atoms and acidity on RTP were studied in detail. The experimental results showed that purine derivatives have analogous spectra. The maximal excitation wavelengths were round 280 nm, the maximal emission wavelengths were round 430 nm. For purine derivatives I- is a widely used heavy atom. The effect of pH on RTP intensity is related to the molecular structure.
【关键词】 滤纸基质;
室温燐光;
嘌呤类化合物;
【Key words】 Room temperature phosphorescence; purine derivatives; solid substrate;
【Key words】 Room temperature phosphorescence; purine derivatives; solid substrate;
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1998年09期
- 【分类号】O656.31
- 【被引频次】4
- 【下载频次】70