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12种嘌呤类化合物的滤纸基质室温燐光法研究

Solid Surface Room Temperature Phosphorescence of Twelve Purine Derivatives

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【作者】 尚晓红董川朱若华晋卫军魏雁声刘长松

【Author】 Shang Xiaohong, Dong Chuan, Zhu Ruohua, Jin Weijun, Wei Yanshang, Liu Changsong (Department of Chemistry, Shanxi University, Taiyuan 030006)

【机构】 山西医科大学公共卫生学院山西大学化学系!太原030006

【摘要】 较为详细地研究了12种嘌呤类化合物以滤纸为基质的室温燐光(RTP)光谱特性与分子结构的关系,以及重原子效应和酸度效应对RTP的影响。

【Abstract】 The solid surface room temperature phosphorescence (SS-RTP) of twelve purine derivatives using China-made filter paper as solid substrate was given. The relation between molecular structure and spetrum, the effects of heavy atoms and acidity on RTP were studied in detail. The experimental results showed that purine derivatives have analogous spectra. The maximal excitation wavelengths were round 280 nm, the maximal emission wavelengths were round 430 nm. For purine derivatives I- is a widely used heavy atom. The effect of pH on RTP intensity is related to the molecular structure.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1998年09期
  • 【分类号】O656.31
  • 【被引频次】4
  • 【下载频次】70
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