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吸附杂多化合物对亚硝酸根的电催化还原
Electrocatalytic Reduction of Nitrite With Heteropolyanions Deposited on Carbon Electrodes
【摘要】 详细地研究了吸附在热解石墨电极表面的SiMo12O404-以及Dy(SiMo11O39)213-和吸附在玻碳电极表面的P2W18O626-的电化学行为,结果表明这些杂多化合物修饰电极在酸性条件下均对NO2-的还原有很好的催化作用,其催化电流与NO2-的浓度的平方根里线性关系。
【Abstract】 Electrochemical behavior of Dawson-type P2W18O626- deposited on a glassy carbon electrode, Keggin-type SiMo12O404- and its derivative Dy (SiMo11O39 )213- deposited on a pyrolytic graphite electrode was described. All these modified electrodes displayed catalytic activity for nitrite reduction in acidic solutions and the catalytic current is linear to the square root of nitrite concentration.
【关键词】 杂多化合物;
电催化;
亚硝酸根;
化学修饰电极;
【Key words】 Heteropolyanions; electrocatalysis; nitrite; chemically modified electrode;
【Key words】 Heteropolyanions; electrocatalysis; nitrite; chemically modified electrode;
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1998年06期
- 【分类号】O646
- 【被引频次】29
- 【下载频次】181