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电荷注入检测器-端视等离子体原子发射光谱中分析动态范围

Analytical Dynamic Range in Atomic Emission Spectrometry With Axially Viewed Plasma and Charge Injection Array Detector

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【作者】 辛仁轩赵玉珍施洪钧

【Author】 Xin Renxuan (TSinghua University, Beijing 100084) Zhao Yuzhen, Shi Hongjun (Institute of Physics, Chinese Academy of Sciences, Beijing 100080)

【机构】 清华大学核能研究院!北京100084中国科学院物理研究所!北京100080

【摘要】 实验研究了电荷注入检测器(CID)-端视电感耦合等离子体(AVICP)光谱中分析动态范围,测量了Al、B、Be、Cd、Cu、Co、Fe、Li、Sr、V、K、Sr等12个元素的不同光谱级次的44条分析工作曲线。结果表明,分析动态范围为4~5个数量级,无明显自吸收,Lomakin公式的自吸收系数b=1,说明在CID-AVICP光谱中有较宽的分析动态范围。

【Abstract】 In this paper the analytical linear ranges of calibration graphs for a new type emission spectrometer with two dimensional charge injection detector and axially viewed plasma were investigated. Calibration graphs for Al, Cd, Cu, Co, Fe, Li, Sr, V, K, Sr, Be, B in different spectral order were examined. The results showed that linear ranges are over four orders of magnitude and no self-reversal or self-absorption is found under concentration at 100-1000 mg/L. The self-absorption coefficient b for Lomakin equation has been determinad and the value is approximately equal to 1.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1998年01期
  • 【分类号】O657.3
  • 【被引频次】5
  • 【下载频次】60
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