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氟锆酸盐玻璃中Tm3+离子的红外光谱性质
INFRARED OPTICAL PROPERTIES OF Tm 3+ IN FLUOROZIRCONATE GLASS
【摘要】 根据Tm3+离子的吸收光谱,计算了在氟锆酸盐玻璃中Tm3+的Judd-Ofelt参数和红外跃迁3F4→3H4,3H4→3H6和3F4→3H5的自发跃迁几率,研究了Tm3+的红外发射光谱和它的交叉弛豫过程,讨论了离子浓度对红外发光强度的影响,并计算了这些跃迁的发射截面.
【Abstract】 In the work, we have calculated Judd Ofelt parameters and the spontaneous emission probabilities of the transitions 3F 4→ 3H 4, 3H 4→ 3H 6, and 3F 4→ 3H 5, according to the absorption of Tm 3+ in the fluorozirconate glass. The three infrared emission spectra of Tm 3+ and the cross relaxation have beem investigated. The effect of the Tm 3+ concentration on the infrared emission intensities has been discussed. The emission cross sections of those transitions have been evaluated.
【关键词】 红外发光;
Tm3+激活离子;
氟锆酸盐玻璃;
【Key words】 infrared fluorescence; Tm 3+ activator; fluorozirconate glass;
【Key words】 infrared fluorescence; Tm 3+ activator; fluorozirconate glass;
- 【文献出处】 发光学报 ,CHINESE JOURNAL OF LUMINESCENCE , 编辑部邮箱 ,1998年01期
- 【分类号】O482.31
- 【被引频次】3
- 【下载频次】85