【摘要】 2-芳氨基苄基（或甲基）环己酮（1）与羟胺盐酸盐在过量氢氧化钠的乙醇和水溶液中回流，转变为2-芳氨基苄基（或甲基）环己酮肟（2），（2）可能为E或Z构型．在多聚磷酸存在下，用甲苯为共溶剂，（2）能顺利进行Bechmann重排反应，得到4个2-芳氨基苄基－5－己内酰胺和3个2－芳氨基甲基－5－己内酰胺（3），均为未见文献报导的新化合物．用元素分析，MS，IR，1HNMR，13CNMR分析确定了它们的结构．（3）的结构证实了（2）为Z－构型．更多还原

【Abstract】 2-arylaminobenzyl(or methyl)-cyclohexanone (1) is prepared diedy by Mannich reaction. (1) can be converted to 2-arylarninobenzy 1 (or methyl) cyclohexanoneoxime (2) by refluxing with hydroxylamine hydrochloride and exass sodium hydroxide in ethanol-H2O solution. When (2) are treated with PPA and using toluene as cosolvent, they rearmnge to four new 2-aryaminobenzylmethyl-5-caprolactam and three new 2-arylandnornethyl-5-capro- lactam (3). The structure of (3) is dedued by elemental analysis, MS, IR, 1HNMR and 13CNMR. The structure of (3) confirms that (2) is Z configuration.更多还原