【摘要】 以季戊四醇为原料经氯化、碱性关环、取代叠氮化合成了３，３－双（叠氮甲基）氧杂环丁烷，采用三氟化硼乙醚在０℃引发３，３－双（叠氮甲基）氧杂环丁烷和四氢呋喃本体聚合，合成了具有能量特征的叠氮共聚醚并用ＩＲ和１ＨＮＭＲ表征了分子结构，运用１３ＣＮＭＲ和ＧＰＣ分析了聚合物的分子量和端基性质。更多还原

【Abstract】 Bis(azidomethyl)oxetane(BAMO) was prepared by the process of chlorination, ring closing and azido substitution from pentaerythritol. The azido copolymers based on 3,3 bis(azidomethyl)oxetane and tetrahydrofuran(THF) have been synthesized by cationic ring opening polymerization with a Lewis initiator,boron trifluoride etherate(BF 3·Et 2O)and the molecular structure was characterized by IR and 1HNMR. The molecular mass and end group properties were analyzed with GPC and 13 CNMR.更多还原