【摘要】 臭氧氧化法制备镍（Ⅳ）高碘酸盐配合物吴明女每龙军彪李秀玲黄爱红罗裕基（中山大学化学系，广州５１０２７５）关键词镍（Ⅳ）高碘酸盐配合物，臭氧氧化，电子光谱分类号Ｏ６１１．４近１０年来特异高价态化合物的合成和性质的研究倍受化学家和物理学家的重视［１～４...更多还原

【Abstract】 The periodatonickelate(Ⅳ)complex was prepared by using ozone as oxidant, and the absorption at 410nm in its electronic spectra was attributed to ligand to metal charge transfer(LMCT)transition and its spontaneous reduction in aqueous solution was determined to be first order kinetic reaction.更多还原