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1-苯甲酰基-5-芳基-2-硫代双缩脲类化合物的质谱研究
Mass Spectra of 1-Benzoyl-5-Aryl-2-Thiobiurets
【摘要】 本文报道了1-苯甲酰基-5-芳基-2硫代双缩脲类化合物的电子轰击质谱。根据高分辨质谱及联动扫描质谱揭示了该类化合物的质谱裂解途径,结果表明该类化合物均能出现较强的分子离子峰,其基峰为[PhCO]+,裂解主要发生在数基的a-位,而硫羰基的a-位不发生断裂。
【Abstract】 The rnass spectra of 1-benzoyl-5-aryl-2-thiobiurets were reported. The mass spectral fragmentation was proposed on the basis of the high resolution mass spectrometry and the B/E linked scan spectra. The results show that 1-benzoyl-5-aryl-2-thiobiurets have strong molecular ion,the base peak is [PhCO]+,the cleavages take place at Q-position of carbonyl group;on the other hand,the bond between thiocarbonyl group and nitrogen atom can not break in the experimental condition.
【关键词】 1-苯甲酰基-5-芳基-2-硫代双缩脲;
电子轰击质谱;
裂解途径;
【Key words】 1-beznoyl-5-aryl-2-thiobiuret; EIMS; fragmentation;
【Key words】 1-beznoyl-5-aryl-2-thiobiuret; EIMS; fragmentation;
- 【文献出处】 质谱学报 ,JOURNAL OF CHINESE MASS SPECTROMETRY SOCIETY , 编辑部邮箱 ,1997年03期
- 【分类号】O657.6
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