【摘要】 报道了两步合成焦磷酸烯丙酯的方法，以醇为原料制备相应的对甲苯磺酸酯、溴化物或氯化物，然后与焦磷酸氢－三（四－正丁铵）进行焦磷酸化，合成了５种焦磷酸烯丙酯，产品经薄层色谱、核磁共振氢谱和磷谱证实为不含杂质的纯品更多还原

【Abstract】 A two step procedure for synthesis of allylic pyrophosphate esters was used,it involved treatment of the alcohols via the corresponding intermediate compounds such as p toluene sulfonate,bromide or chloride,and then pyrophosphorylation with tris(tetra n butyl amonium)hydrogen pyrophosphate.Five allylic pyrophosphate esters were synthesized.The products,as judged by TLC and 1H, 31 P NMR,are proved to be free of contaminants.更多还原