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反式-2-(4-[2-(4-取代苯基)乙烯基]苯基)-5-(4-联苯基)唑的合成、电子光谱与光性能
Synthesis, Electronic Spectrum and Optical Property of Trans 2 {4 [2 (4 R phenyl)ethenyl]phenyl} 5 (4 biphenyl)oxazole
【摘要】 通过4-RC6H4CHO与2-(4-甲基苯基)-5-(4-联苯基)口恶唑(R=H,Me,Et,i-Pr,i-Bu,Ph,OMe,F,Cl,Br)在碱催化下的缩合反应合成了10个新的反式-2-{4-[2-(4-取代苯基)乙烯基]苯基}-5-(4-联苯基)口恶唑类化合物,经元素分析、IR、UV及MS确定了它们的结构.并测定了荧光发射光谱、荧光量子产率和激光转换效率.
【Abstract】 Ten trans 2 {4 [2 (4 R phenyl)ethenyl]phenyl} 5 (4 biphenyl)oxazoles (R=H, Me, Et, i Pr, t Bu, Ph, OMe, F, Cl, Br) were synthesized. They were identified by elemental analysis、 IR、 UV and MS. Their FL spectra, fluorescence quantum yields and laser conversion efficiencies are reported and discussed.
【关键词】 二芳基唑;
合成;
电子光谱;
激光转换效率;
【Key words】 diaryloxazole; synthesis; electronic spectrum; laser conversion efficiency;
【Key words】 diaryloxazole; synthesis; electronic spectrum; laser conversion efficiency;
【基金】 国家自然科学基金
- 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,1997年03期
- 【分类号】TQ25
- 【下载频次】31