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β-CD与乙酸苄酯包合物的制备及其热分解研究

Preparation of Inclusion Complex of Benzyl Acetate with β-Cyclodextrin and Studies on its Thermal Dissociation

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【作者】 田圣军成庆堂席国喜娄向东李靖华

【Author】 Tian Shengjun;Cheng Qingtang; Xi Guoxi; Lou Xiangdong; Li Jinghua(Department of Chemistry Henan Normal University Xinxiang 453002)

【机构】 河南师范大学化学系!新乡453002

【Abstract】 The inclusion complex of benzyl acetate (BA) with β-cyclodextrin (β-CD) was pre-pared and was confirmed by thermal analysis and X-ray diffeaction (XRD). The composition of thecomplex was identified by thermogravimetry (TG) and elemental analysis as β-CD.C9H10O2 .6H2O.TG and DSC studies showed that the thermal dissociation of β-CD.C9H10O2.6H2O took place inthree stages: the dehydration occurred at 80-120 ℃; the dissociation of β-CD.C9H10O2 occurredat 245-270℃; and the decomposition of β-CD began at 285℃. The kinetics of dissocia-tion of β-CD.C9H10O2 was studied by means of TG. The results showed that the dissociation ofβ-CD.C9H10O2 was controlled by a two-dimensional random nucleation and subsequent growthprocess (A3), the activation cnergy E is 172.85kJ.mol-1, and the pre-exponential factor A is1.1392×1016.min- 1.

  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1997年05期
  • 【分类号】O636
  • 【被引频次】9
  • 【下载频次】56
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