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热缩聚煤沥青压型制备分子筛炭膜(Ⅲ)─—表面涂层法制备分子筛炭膜
MANUFACTURING CARBON MOLECULAR SIEVE MEMBRANE FROM HEAT-TREATMENT COAL PITCH BY PRESSING (Ⅲ)──PREPARING CARBON MOLECULAR SIEVE MEMBRANE BY SURFACE COATING
【摘要】 表面涂层法是制备分子筛炭膜的有效方法、以酚醛树脂的乙醇溶液作为涂层液对炭膜基板进行处理,制得适合H2/CO2分离的分子筛炭膜。结果表明,适宜的涂层液浓度为30%(Vol),涂层处理四次制得分子筛炭膜。H2与CO2的渗透速率分别为2.66×10-5和2.22×10-6cm3(STP)/cm2·s.cmHg,二者的分离系数可达到11.7。
【Abstract】 Surface coating is one of effective methods for preparing carbon molecular sieve membrane (CMSM ). CMSM was obtained from treating carbon membrane substrate with PF-alcohol solution.The CMSM is suitable for separating H2/CO2. Results show that perfect coating concentration is 30%(Vol ). CMSM can be prepared after coating 4 times. The permeation rates of H2 and CO2 are about 2. 66×10-5 and 2. 22× 10-6 cm3 (STP ) /cm2·s·cmHg. The separation factor is about 11. 7.
【关键词】 表面涂层;
分子筛炭膜;
气体分离;
【Key words】 Surface coating; carbon molecular sieve membrane; gas separation;
【Key words】 Surface coating; carbon molecular sieve membrane; gas separation;
【基金】 国家教委博士点基金
- 【文献出处】 炭素技术 ,CARBON TECHNIQUES , 编辑部邮箱 ,1997年01期
- 【分类号】TQ424
- 【被引频次】3
- 【下载频次】89