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紫茎泽兰化学成分的研究(Ⅰ)

STUDIES ON THE CHEMICAL CONSTITUENTS OF EUPATORIUM ADENOPHORUM SPRENG

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【作者】 朱正方杨光忠栗国强

【Author】 Zhu Zhengfang, Yang Guangzhong, Li Guoqiang (Institute of Organic Synthesis,Central Normal University, Wuchang 430070)

【机构】 华中师范大学有机合成所华中师范大学有机合成所 武昌 430070武昌 430070武昌 430070

【摘要】 从云南紫茎泽兰(Eupatorium aclenophorum Spreng)茎、叶中分出10个化合物,经波谱(IR,MS,1H-NMR,13C-NMR)分别鉴定为9-oxo-ageraphorone(Ⅰ),9β-hydroxy-ager-aphorone(Ⅱ),表木栓醇(epifriedelinol,Ⅲ),豆甾醇(stigmasterol,Ⅳ),正二十八烷酸(octa-cosanoic acid,V),β-胡萝卜甙(β-daucosterol,Ⅵ),邻羟基桂皮酸(O-hydroxy cinnamic acid,Ⅶ),阿魏酸(ferulic acid,Ⅷ),咖啡酸(caffeic acid,Ⅸ),2-异丙烯基-5-乙酰基-6-羟基苯骈呋喃的乙酰化物(2-isopropenyl-5-acetyl-6-hydroxybenzofuran acetate,Ⅹ)。化合物(Ⅲ~Ⅹ)均系首次从该植物中分离到。

【Abstract】 Ten compounds have been isolated from the stem and leaves of Eupatorium adenophorum Spreng. By the IR,MS,1HNMR,13CNMR, DEPT and element analysis, the structures of compounds were identified to be 9-oxo-ageraphorone ( I ), 9β-hydroxy-ageraphorone (Ⅱ), epifriedelinol (Ⅲ), stigmasterol (Ⅳ ) , octacosanoic acid (Ⅴ) , β-daucosterol (Ⅵ) ,o-hydroxy cinnamic acid ( Ⅶ) ,ferulic acid (Ⅷ) caffeic acid (Ⅸ) ,2-isopropenyl-5-acetyl-6-hydroxy benzofuran acetate ( X ) respectively, The compounds (Ⅲ)- ( X ) had not previously been isolated from the plant, the biological activity results of the compounds ( I ) and (Ⅱ) were reported.

【基金】 国家自然科学基金
  • 【文献出处】 天然产物研究与开发 ,Natural Product Research and Development , 编辑部邮箱 ,1997年03期
  • 【分类号】O629
  • 【被引频次】35
  • 【下载频次】462
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