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防老剂H对丁羟推进剂粘合剂体系形态结构和力学性能的影响
EFFECT OF ANTIOXIDANT H ON MORPHOLOGICAL STRUCTURE AND MECHANICAL PROPERTIES OF HTPB PROPELLANT BINDERS
【摘要】 运用透射电镜(TEM)和动态力学分析(DMA)研究了丁羟推进剂粘合剂体系的形态结构,发现在该体系中存在硬段、软段两相分离结构;防老剂H(N,N’-二苯基对苯二胺)的加入,引入了更多的硬段微区,使两相结构更为清晰;解释了防老剂H能大幅度提高粘合剂体系力学性能的原因。
【Abstract】 The morphological structures of HTPB propellant binders have been studied bytransmission electron microscopy (TEM ) and dynamic mechanical analysis (DMA). It is found thatthere are microphase segregation structures of hard and soft segments in the binders. Harder segmentdomains are brought in binders by adding antioxidant H (N, N’-diphenyl-p-phenylene dlamine)andthe microphase segregation structures become clearer. We have explained the reason that antioxidantH can greatly improve mechanical properties of HTPB propellant binders.
【关键词】 端羟基聚丁二烯推进剂;
推进剂粘合剂;
推进剂防老剂;
形态结构~+;
力学性能;
【Key words】 Hydroxy terminated polybutadiene propellant; Propellant binder; Propellant antioxidant; Morphological structure; Mechanical perfomance;
【Key words】 Hydroxy terminated polybutadiene propellant; Propellant binder; Propellant antioxidant; Morphological structure; Mechanical perfomance;
【基金】 课题获航天工业总公司科技进步三等奖
- 【文献出处】 推进技术 ,JOURNAL OF PROPULSION TECHNOLOGY , 编辑部邮箱 ,1997年03期
- 【分类号】V512.3
- 【被引频次】13
- 【下载频次】179