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以稻壳为原料制取氟硅酸钠

Preparation of Sodium Fluorosilicate with Rice Husk

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【作者】 延国宁; 马登民; 隋桂花;

【Author】 Yan\ Guoning\ \ Ma\ Dengmin\ \ Sui\ Guihua(Shenyang Institute of Chemical Technology, Shenyang\ 110021)

【机构】 沈阳化工学院;

【摘要】 稻壳燃烧后的灰分中含硅酸酐和无定形硅达95%,与萤石粉充分混合,在浓硫酸的作用下生成气态SiF4和硫酸钙.SiF4经水吸收得固相硅胶和氟硅酸溶液,氟硅酸溶液与食盐作用生成氟硅酸钠和盐酸.因过程中的中间产品为气相,故最终产品的纯度一步可达99%,收率为62%.本法对以稻壳为燃料装置中灰渣的利用有很大的意义.

【Abstract】 The ash, which remains after burning rice husk, contains 95 % silica and amorphous silicon. Mixing the ash with fluorite powder in the presence of concentrated sulfuric acid, gaseous SiF 4 and calcium sulfate were obtained. Solidified silica gel and fluorosilicic acid solution can be prepared by absorption of SiF 4 in aqueous solution. Then the fluorosilicic acid solution reacts with salt to produce sodium fluorosilicate and hydrochloric acid. As the intermediate produced in the process is a gaseous form, so that the purity of sodium fluorosilicate may reach 99 % and the yield is 62 %. This method is significant for the utilization of rice husk ash.

【关键词】 稻壳; 氟硅酸钠; 萤石;
【Key words】 rice husk; \ sodium fluorosilicate; \ fluorite;
  • 【文献出处】 沈阳化工学院学报 ,JOURNAL OF SHENYANG INSTITUTE OF CHEMICAL TECHNOLGY , 编辑部邮箱 ,1997年03期
  • 【分类号】TQ914.3
  • 【被引频次】9
  • 【下载频次】97
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