【摘要】 研究了［ＢＡ］、陈化时间对ＢＡ／ＴｉＣｌ４／ＩＢ／ＣＨ２Ｃｌ２体系聚合反应的影响。通过产物ＧＰＣ谱图和紫外、ＦＴＩＲ光谱分析，证明体系存在Ｈ２ＯＴｉＣｌ４ＢＡＴｉＣｌ４←ＢＡ络合体系。当［ＢＡ］＞６×１０－２ｍｏｌ／Ｌ，［ＴｉＣｌ４］／［ＢＡ］＝４０／１时，ＢＡ能有效抑制ＴｉＣｌ４和Ｈ２Ｏ的络合，投料顺序为先加引发剂ＢＡ，然后加入共引发剂ＴｉＣｌ４，为阳离子聚合反应的进一步研究提供了参考价值。更多还原

【Abstract】 The effect of and the ageing time on carbocationic polymerization of BA/TiCl4/IB/CH₂Cl₂ system were investigated. It was demostrated that there coexist H₂O→TiCl₄BATiCl₄←BA complexing competition. BA can effectively restrict the complexation of TiCl₄ and H₂O. The addition sequence is that the initiator BA is added at first, then coinitiator TiCl₄ is added. It affords reference value to further study carbocationic polymerization.更多还原