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双重负载双金属催化剂催化的硝基苯氢化还原
Hydrogenation of Nitrobenzene by Dually Supported Bimetallic Catalysts
【摘要】 制备了易于从反应体系中分离的高活性、高选择性双重负载双金属催化剂[0.80Pd-0.20Pt/PVP]/载体,并用于硝基苯还原反应。其中以Al2O3为载体的催化剂具有最高活性。考察了钯负载量、乙酸钠用量、溶剂等因素对催化剂活性和稳定性的影响。
【Abstract】 Dually supported bimetallic catalysts,[0 80Pd 0 20Pt/PVP]/support,were prepared and used in the hydrogenation of nitrobenzene.Catalysts [0 80Pd 0 20Pt/PVP]/Al 2O 3 was the best one among them.The effects of the loading level of Pd,the amount of sodium acetate and the solvent used on the reaction were investigated.The catalyst[0 80Pd 0 20Pt/PVP]/Al 2O 3 exhibited high activity,selectivity and stability in the hydrogenation of nitrobenzene under the favorable reaction conditions.
【关键词】 双重负载;
双金属催化剂;
氢化;
硝基苯;
【Key words】 dually supported; bimetallic catalyst; hydrogenation; nitrobenzene;
【Key words】 dually supported; bimetallic catalyst; hydrogenation; nitrobenzene;
- 【文献出处】 石油化工 ,PETROCHEMICAL TECHNOLOGY , 编辑部邮箱 ,1997年11期
- 【分类号】O625
- 【被引频次】9
- 【下载频次】168