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双重负载双金属催化剂催化的硝基苯氢化还原

Hydrogenation of Nitrobenzene by Dually Supported Bimetallic Catalysts

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【作者】 杨斌余正坤徐筠廖世健余道容

【Author】 Yang Bin,Yu Zhengkun,Xu Yun,Liao Shijian and Yu Daorong (Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023)

【机构】 中国科学院大连化学物理研究所

【摘要】 制备了易于从反应体系中分离的高活性、高选择性双重负载双金属催化剂[0.80Pd-0.20Pt/PVP]/载体,并用于硝基苯还原反应。其中以Al2O3为载体的催化剂具有最高活性。考察了钯负载量、乙酸钠用量、溶剂等因素对催化剂活性和稳定性的影响。

【Abstract】 Dually supported bimetallic catalysts,[0 80Pd 0 20Pt/PVP]/support,were prepared and used in the hydrogenation of nitrobenzene.Catalysts [0 80Pd 0 20Pt/PVP]/Al 2O 3 was the best one among them.The effects of the loading level of Pd,the amount of sodium acetate and the solvent used on the reaction were investigated.The catalyst[0 80Pd 0 20Pt/PVP]/Al 2O 3 exhibited high activity,selectivity and stability in the hydrogenation of nitrobenzene under the favorable reaction conditions.

  • 【文献出处】 石油化工 ,PETROCHEMICAL TECHNOLOGY , 编辑部邮箱 ,1997年11期
  • 【分类号】O625
  • 【被引频次】9
  • 【下载频次】168
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