【摘要】 合成了什含四氮杂大环配体和O，O’－二煌基二硫代磷酸根的铜配合物[Cu（hmtade）｛SSP（OR）2｝2」（hmtade＝5，7，7，12，14，14-六甲基-1，4，8，11-四氮杂环十四-4，11－二烯，R＝C6H5，2－naphthyl，CeH5CH2CH2，CyClohexyl），用元素分析、摩尔电导、红外光谱、电子光谱和差热分析对其结构进行了表征。研究结果表明：配合物均为非电解质，O，O’-二烃基二硫代磷酸根作为单齿配体对铜中心配位。对四氮杂大环的构型和配合物的差热分析进行了讨论。更多还原

【Abstract】 Four copper complexes [Cu(hmtade) {SSP (OR)2 } 2] (hmtade = 5, 7,7, 12, 14, 14-hexamethyl-1 ,4, 8, 11-tetraazacyclotetradeca-4, 11-diene; R = Phenyl, 2-naphthyl, 2-phenylethyl and cyclohexyl) are synthesized and characterized by elmental analysis, molar conductivity, infrared spectra, electronic spectra and TG-DTA analysis.The results indicate that all complexes are non-electrolytes in DMSO and O, O’-dialkyldithiophosphoric acid radicals as monodentatet ligands coordinate to copper atom.Tetraazamacrocyclic configuration and TG-DTA curves of the complexes are also discussed.更多还原