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外加无机电解质对煤浆性质调控作用的研究

REGULATING ACTION OF INORGANIC ELECTROLYTES ON PROPERTIES OF COAL WATER SLURRY

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【作者】 孙成功谢亚雄李保庆

【Author】 Sun Chenggong Xie Yaxiong Li Baoqing (State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Aacademy of Sciences, Taiyuan)

【机构】 中国科学院山西煤炭化学研究所煤转化国家重点实验室

【摘要】 考察了数种无机电解质对煤浆分散体系流变特性的影响。结果发现,煤浆的流变特性不仅与电解质种类有关,还取决于煤质特征。某些煤种,适量的无机电解质可使浆体的屈报胀塑性转化为屈服假塑性。由于二价金属盐在改善浆体流变性的同时不会使浆体粘度有较大增加,其性能优于三价金属盐,一价金属盐要求电解质浓度很高而不宜采用。无机电解质的调控作用还与离子质量有关。同时发现,能够改善浆体流变性的金属离子未必对浆体有稳定化作用,而有利于浆体稳定化作用的金属离子未必能在较低的临界浓度下改善浆体的流变性而不使浆体粘度显著增大。

【Abstract】 The regulating action of several inorganic electrolytes on properties of coal water slurries with different coals were systematically investigated in detail The results indicated that electrolytes are of great importance in regulating the rheological behaviour of the slurry, however, their regulating behaviour upon coal water slurry is strongly dependent on both electrolyte compositions, especially its contained cations, and the properties of coals For some kinds of coals, the dilatant behaviour of their slurries could be easily changed and transferred into the pseudoplastic behaviour, the electrolytes with twovalence cations are much better than those with threevalence cations because they cause no sharp rise in slurry viscosity while changing the slurry rheological behaviour On the contrary, for some kinds of coals, the addition of any kind of electrolytes investigated resulted in a much stronger dilatant behaviour in their slurries It was also observed that some electrolytes are effective in improving the slurry rheological beahviour even at low critical concentrations but detrimental to slurry stability, while some electrolytes favour the slurry stability but harm the rheological behaviour

  • 【文献出处】 燃料化学学报 ,JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY , 编辑部邮箱 ,1997年02期
  • 【分类号】TQ534.4
  • 【被引频次】30
  • 【下载频次】91
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