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液晶双马来酰亚胺/环氧树脂共聚物的制备

PREPARATION OF THE COPOLYMERS OF LC BISMALEIMIDE/LC EPOXY RESIN

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【作者】 米军张欣茹李祝刘孝波蔡兴贤

【Author】 M Jun; Zhang Xingyuan; Li Zhu(Department of Polymer Materials, Sichuan Union University, Chengdu, 610065)Mi Jun; Zhang Xingyuan; U ZhuLiu Xinobo; Cai Xingxian(Analyst and Test Center, Sichuan Union university, Chengdu, 610065)

【机构】 四川联合大学高分子材料系四川联合大学分析测试中心

【摘要】 本文采用含柔性链(C10)的液晶双马来酰亚胺和含联苯基的液晶环氧树脂合成共聚物,经FTIR、DSC、偏光显微镜、SEM表征了该共聚物的结构与液晶特征。结果表明该共聚物具有较好热致液晶性,其液晶织态呈向列型织构,亦能保留在交联网络结构中。

【Abstract】 The copolymers were preparated from liquid crystalline (LC) bisrnaleimide containing flexible chain (C10) and LC epocy resin containing biphenyl group, and were characterized by means of DSC, DTA, FT-IR spectroscopy and polarized light whcroscope (PLM). The FT -IR spectroscopy showed the copolymerization between LC bisrnaleimide and LC epoxide.The good thermotropic LC behaviors, nernatic phase and LC thermoset network were characterized by PLM, DSC and DTA before or after curing reaction. The SEM showed that its fracture toughness was increased by copolymerization

【基金】 国家自然科学基金!59373145
  • 【文献出处】 热固性树脂 ,THERMOSETING RESIN , 编辑部邮箱 ,1997年03期
  • 【分类号】O633
  • 【被引频次】20
  • 【下载频次】146
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