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苯并二氢呋喃类木脂素NMR谱的研究
THE STUDIES ON THE NMR SPECTRA OF DIHYDROBENZOFURAN LIGNANS
【摘要】 用2DHMR技术研究了从水飞蓟素(Silymarin)中分离的一个苯并二氢呋喃类木脂素的结构,证实该类化合物的取代基位置可用COLOC谱确定.同时研究了该类化合物以DMSO-d6为溶剂的PMR谱的特征.另外对Balanophonin的PMR谱进行了详细归属.
【Abstract】 The chemical structure of dihydrobenzofuran lignans Balanophonin(1) was studied by 2D NMR spectra analyses. It was observed that the attached position of methoxyl and hydroxyl groups in A ring can be determined by analysing the cross peaks in COLOC spectrum. Meanwhile, the speciality of PMR spectra (in DMSO-d6) of this kind of compounds was studied. All the proton signals of Balanophonin (1) were assigned in detail also.
【关键词】 水飞蓟素;
苯并二氢呋喃类木脂素;
取代位置;
COLOC;
PMR;
【Key words】 Silymarin; Dihydrobenzofuran lignans; Attached position; COLOC; PMR;
【Key words】 Silymarin; Dihydrobenzofuran lignans; Attached position; COLOC; PMR;
- 【文献出处】 波谱学杂志 ,CHINESE JOURNAL OF MAGNETIC RESONANCE , 编辑部邮箱 ,1997年05期
- 【分类号】O626
- 【被引频次】4
- 【下载频次】214