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膦磺酸型阻垢剂结构与性能探讨

A STUDY ON THE STRUCTURE AND SCALE INHIBITOR PERFORMANCE OF PHOSPHATED SULPHONATE ACID

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【作者】 韩应琳; 赵任辉; 王卉; 卫春; 马迎军; 杨文忠;

【Author】 Han Yinglin\ Zhao Renhui\ Wang Hui\ Wei Chun Ma Yingjun\ Yang Wenzhong [WT5”BZ]Department of Applied Chemsitry, Nanjing University of Chemical Technology, Nanjing, China, 210009

【机构】 南京化工大学应用化学系;

【摘要】 探讨了6种不同官能团结构膦磺酸的阻磷酸钙垢及稳定锌的性能,对膦磺酸、有机膦及磺酸共聚物进行阻垢分散性能比较,结果表明:分子中膦酸基增多可增强阻垢分散的效果,4mg/L膦甲基磺酸或膦乙基磺酸的阻碳酸钙性能优于ATMP、HEDP和磺酸共聚物。结果还表明:亚甲基磺酸基或乙基磺酸基能增强有机膦酸阻磷酸钙垢,稳定锌和分散氧化铁的性能。

【Abstract】 The performace of scale inhibiting Ca 3(PO 4) 2 and stabilized zinc (Zn 2+ ) are studied through six phosphated sulphonate acids different in the structure of functional groups, and the performance contrasts of scale inhibition and dispersion for sulphonate acid, organic phosphate and sulfoacid copolvner are also studied. Experimental results show that the more phosphated acid in the molecule, the more the effect of scale inhibition and dispersion. Phosphated methyl sulphonate acid and phosphated ethyl sulphonate acid are superior to ATMP, and HEDP or sulphonate copolymer in inhibiting CaCO 3 scales when their concentrations are equal to 4 mg/L. Experimental results also demonstrate that methyl sulphonate acid or ethyl sulphonate acid can enforce organic phosphate acid in its performance of inhibiting Ca 3(PO 4) 2, stabilizing Zn 2+ and dispersing Fe 2O 3.

【基金】 国家科委专用化学品资助
  • 【文献出处】 南京化工大学学报(自然科学版) ,JOURNAL OF NANJING UNIVERSITY OF CHEMICAL TECHNOLOGY , 编辑部邮箱 ,1997年03期
  • 【分类号】TG174
  • 【被引频次】13
  • 【下载频次】166
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