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聚乙烯醇序列结构的13C NMR测定
13 C NMR Measurement of the Sequence Structure for PVA
【摘要】 根据不同结构单元主链CH2化学位移和峰强度的不同,采用二单元组定量计算方法,分别计算不同聚乙烯醇(PVA)样品的一单元和二单元结构相对含量及各结构单元的数均序列长度和嵌段含量,并详细给出了残留乙酰基的序列分布。
【Abstract】 According to the contribution of main chain CH 2 units to the peaks, many sequence structural data, including the concentration of diads, monomer units and their blocks and the number average sequence lengths of each monomer unit, were cal culated form the equations for diad concentrations in terms of peak intensity. Furthermore, the sequence distribution of residual acetoxy were determined in detail.
- 【文献出处】 辽宁化工 ,LIAONING CHEMICAL INDUSTRY , 编辑部邮箱 ,1997年02期
- 【分类号】O657
- 【被引频次】2
- 【下载频次】158