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大孔膦酸树脂吸附镧的研究

STUDIES ON THE SORPTION OF MACROPOROUS PHOSPHONIC ACID RESIN FOR LANTHANUM

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【作者】 熊春华舒增年陈义镛

【Author】 Xiong Chunhua; Su Zhengnian (Department of Chemistry, Lishui Teachers College, Zhejiang 323000) Chen Yiyong (Department of Chemistry, Hangzhou University, Hangzhou 310028)

【机构】 丽水师范专科学校化学系!浙江323000杭州大学化学系!杭州310028

【摘要】 本文测定了大孔膦酸树脂对La3+的吸附容量,介质pH、温度、吸附时间等因素对吸附的影响。测得吸附速率常数K298=7.64×10-5S-1,树脂功能基与La3+的络合比为3:1,用化学及红外光谱等方法,得到大孔磷酸树脂吸附La3+的基本参数及其机理。

【Abstract】 The influences of medium PH, sorption temperature, sorption time, etc. on the sorption capacity of macroporous phosphonic acid resin for La3+ were determined. The sorption rate constant was K298 = 7. 64 ×10 - 5 s - 1. The complex ratio of phosphonic groups on the resin to La3+ was 3: 1. The basic sorption parameters and the sorption mechanism of macroporous phosphonic acid resin for La3 + were determined by Chemical analysis and IR spectrometry.

  • 【文献出处】 离子交换与吸附 ,ION EXCHANGE AND ADSORPTION , 编辑部邮箱 ,1997年01期
  • 【分类号】TQ028.14
  • 【被引频次】11
  • 【下载频次】120
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