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磷钨酸催化合成1-萘乙酸甲酯的研究
Study on Synthesis of Methyl- 1-Naphthylacetate with Phosphotungstic Acid Catalyst
【摘要】 研究了以磷钨酸为催化剂,1萘乙酸和甲醇直接酯化合成1萘乙酸甲酯的优化反应条件:催化剂用量为反应液的3%,醇酸摩尔比为16∶1,反应在回流温度下进行3h,酯的收率在96%以上,纯度达996%。
【Abstract】 The optimum conditions have been studied on which the 1naphthylacetic acid and methanol are esterified into methyl 1naphthylacetate in the presence of the phosphotungstic acid catalyst.The catalyst is 3% of feedstock,the mole ratio of alcohol to carboxylic acid is 16∶1,the reaction time is 3 hours and reaction temperature is 80℃.Under the optimum conditions the yield and purity of esters are above 96% and 99.6% respectively.
【基金】 陕西省教委专项科研基金
- 【文献出处】 精细化工 ,FINE CHEMICALS , 编辑部邮箱 ,1997年06期
- 【分类号】TQ452
- 【被引频次】31
- 【下载频次】65