节点文献

磷钨酸催化合成1-萘乙酸甲酯的研究

Study on Synthesis of Methyl- 1-Naphthylacetate with Phosphotungstic Acid Catalyst

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 杨德全王升文刘启瑞高利军张小龙

【Author】 Yang Dequan,Wang Shengwen,Liu Qirui,Gao Lijun,Zhang Xiaolong (Department of Chemistry, Yan ,an University,Postcode 716000)

【机构】 延安大学化学系

【摘要】 研究了以磷钨酸为催化剂,1萘乙酸和甲醇直接酯化合成1萘乙酸甲酯的优化反应条件:催化剂用量为反应液的3%,醇酸摩尔比为16∶1,反应在回流温度下进行3h,酯的收率在96%以上,纯度达996%。

【Abstract】 The optimum conditions have been studied on which the 1naphthylacetic acid and methanol are esterified into methyl 1naphthylacetate in the presence of the phosphotungstic acid catalyst.The catalyst is 3% of feedstock,the mole ratio of alcohol to carboxylic acid is 16∶1,the reaction time is 3 hours and reaction temperature is 80℃.Under the optimum conditions the yield and purity of esters are above 96% and 99.6% respectively.

【基金】 陕西省教委专项科研基金
  • 【分类号】TQ452
  • 【被引频次】31
  • 【下载频次】65
节点文献中: 

本文链接的文献网络图示:

本文的引文网络