【摘要】 系统研究了正常及反常赖政－悌曼反应（NormalorAbnormalReliner－TiemannReavction，NRYorART）；研究了相转移住化方法和超声波辐射技术及其在正常Reliner—Tiemann（NRT）反应中的应用，从而使反应条件温和，效率增加，对邻比大，时间缩短，取得较好收效。更多还原

【Abstract】 Systematic investigation was made on normal and abnormal Reimer-tiemann (NRT,ART) reactions and on appications of phase-transfer catalysis (PTC) and ultras onicirradi-ation (USI) techniques to organic synthesis. In this paper, phase-transfercatalysis (PTC)methid and ultrasonic irradiation technique and their combination wereused for performingthe normal Reimer-Tiemann (NRT) reaction. The introduction of thecombination tech-nique took serval advantages: (1) the NRT reaction occours more easily which can be per-formed at room-temperrature (at about 30℃) ; (2) the total yields of twohydroxy-benzaldehydes arises to be higher; (3) the amount of para-substituted priductincreases by alarge scale; (4) the reaction time becomes much shorter.These results show a good applicable prospect of PTC and USI techniques in organnicsynthesis.更多还原