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Electron transfer reaction of meso-phenyl-tetrabenzo-porphyrinato-zinc and dicyanobenzene at low temperature

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【作者】 王夺元胡敏学胡凌志赵理曾卢振中聂玉昕

【Author】 WANG Duoyuan,HU Minxue,HU Lingzhi(Laboratory of Photochemistry,Institute of Photographic Chemistry,Chinese Academy of Sciences,Beijing 100101,China)ZHAO Lizheng,LU Zhenzhong and NIE Yuxin( Laboratory of Optical Physics,Institute of Physics,Chinese Academy of Sciences,Beijing 100080,China)

【机构】 Laboratory of PhotochemistryInstitute of Photographic ChemistryChinese Academy of SciencesBeijing 100101ChinaLaboratory of Optical PhysicsInstitute of PhysicsBeijing 100080China

【摘要】 <正> The behavior of photon-gated spectral hole burning with meso-phenyl-tetrabenzoporphyrinato-zinc as electron donor and dicyanobenzene as electron acceptor dispersed in polymethylmethacrylate was investigated.The data of absorption spectrum of the photoproduct acquired through photon-gated hole burning process by high power density and long hole burning time at 20 K were given The mechanism of photomduced donor-acceptor electron transfer for the iarget system in photon-gated spectral hole burning was demonstrated.

【Abstract】 The behavior of photon-gated spectral hole burning with meso-phenyl-tetrabenzoporphyrinato-zinc as electron donor and dicyanobenzene as electron acceptor dispersed in polymethylmethacrylate was investigated.The data of absorption spectrum of the photoproduct acquired through photon-gated hole burning process by high power density and long hole burning time at 20 K were given The mechanism of photomduced donor-acceptor electron transfer for the iarget system in photon-gated spectral hole burning was demonstrated.

【基金】 Project supported by the National Natural Science Foundation of China
  • 【文献出处】 Science in China(Series B) ,中国科学B辑(英文版) , 编辑部邮箱 ,1997年02期
  • 【分类号】O627
  • 【下载频次】15
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