【摘要】 标题化合物，线性多聚的三（μ-β-苯基丙烯酸）镧，被合成并得到晶体．X-衍射结构分析表明[La（β-C6H5HCOO）3]为三方晶系，R3c空间群，晶体学数据：a=13．344（1）A，α=116.13（1）°V=1182．2（4）A3，Z=2，Dx=1．63g/cm3，μ=1．85mm-1，F（000）=576．573个可观察的衍射点（Ⅰ＞3σ（Ⅰ）），最终偏差因子R=0．031，Rw=0．036．在每个配位单元中，La与来自六个羧酸根的九个氧原子配位．晶体结构由沿晶胞体对角线方向无限伸展的一维聚合链组成，－La－La-重合于三重轴．更多还原

【Abstract】 The title compound, linear-poly [μ-β-phenylacrylato-O,O’:O’ ) Lanthanum ], has been synthesized and determined by X-ray single-crystal diffraction. [La (β-C6H5CHCHCOO)3] crystallizes in the trigonal, space group R3c. Cell parameters are a= 13. 344 (1 ) A,a= 116. 13 (1 )°,V= 1182. 2 (4) A 3,Z= 2,Dx= 1. 63 g/cm3, μ= 1. 85mm-1,F(000) = 576. The structure was refined to an R of 0. 031 and Rw of 0. 036 for 573 observed renections. Each La atom is coordinated with nine O atoms from six carboxylato groups. The crystal structure consists of one-dimensional polymeric chains with La atoms lying on thethree-fold axis of chains at a La-La distance of 3. 991 (1) A .更多还原