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液-液萃取法从钨中分离钽

SEPARATION OF TANTALUM FROM TUNGSTEN BY LIQUID LIQUID EXTRACTION

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【作者】 李宗伟赵之正杨维凡牟万统杨永峰蔡喜臣

【Author】 Li Zongwei Zhao Zhizheng Yang Weifan Mou Wantong Yang Yongfeng Cai Xicheng (Institute of Modern Physics,the Chinese Academy of Sciences,Lanzhou 730000)

【机构】 中国科学院近代物理研究所

【摘要】 用放射化学方法和γ谱测量技术检验了在HNO3-HF体系中用甲基异丁基酮萃取钽的快速化学分离流程。实验结果表明,该流程在HNO3-HF体系中能快速、有效地从14MeV中子轰击天然钨靶样中分离钽,对W的去污系数在104以上。将上述化学流程用于中能18O离子轰击过的钨靶时,从γ谱图发现,除少数元素未被分离外,核反应产生的大部分元素已被分离

【Abstract】 A rapid radiochemical separation procedure is performed using radiochemical separation method and γ spectrum measurement technique.In the procedure,tantalum produced by 14 MeV neutrons bombardment of natural tungsten is extracted by isobutyl methyl ketone from the HF HNO 3 solution.The experimental result shows that this separation procedure is rapid and efficient for separating tantalum from the mixed solution of HF HNO 3 by isobutyl methyl ketone and the decontamination factors are more than 10 4.At the same time,the procedure is also used to separate tantalum from tungsten targets bombarded with intermediate energy ( 18 O).The measured γ spectrum shows that tantalum has been separated from most elements produced in the nuclear reactions except for less elements.

【基金】 中国科学院八五重大课题资助
  • 【文献出处】 核化学与放射化学 ,JOURNAL OF NUCLEAR AND RADIOCHEMISTRY , 编辑部邮箱 ,1997年02期
  • 【分类号】O614.513
  • 【被引频次】3
  • 【下载频次】61
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