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液-液萃取法从钨中分离钽
SEPARATION OF TANTALUM FROM TUNGSTEN BY LIQUID LIQUID EXTRACTION
【摘要】 用放射化学方法和γ谱测量技术检验了在HNO3-HF体系中用甲基异丁基酮萃取钽的快速化学分离流程。实验结果表明,该流程在HNO3-HF体系中能快速、有效地从14MeV中子轰击天然钨靶样中分离钽,对W的去污系数在104以上。将上述化学流程用于中能18O离子轰击过的钨靶时,从γ谱图发现,除少数元素未被分离外,核反应产生的大部分元素已被分离
【Abstract】 A rapid radiochemical separation procedure is performed using radiochemical separation method and γ spectrum measurement technique.In the procedure,tantalum produced by 14 MeV neutrons bombardment of natural tungsten is extracted by isobutyl methyl ketone from the HF HNO 3 solution.The experimental result shows that this separation procedure is rapid and efficient for separating tantalum from the mixed solution of HF HNO 3 by isobutyl methyl ketone and the decontamination factors are more than 10 4.At the same time,the procedure is also used to separate tantalum from tungsten targets bombarded with intermediate energy ( 18 O).The measured γ spectrum shows that tantalum has been separated from most elements produced in the nuclear reactions except for less elements.
【Key words】 Heavy ion nuclear reaction Liquid liquid extraction Rapid chemical separation γ spectrum Decontamination factor;
- 【文献出处】 核化学与放射化学 ,JOURNAL OF NUCLEAR AND RADIOCHEMISTRY , 编辑部邮箱 ,1997年02期
- 【分类号】O614.513
- 【被引频次】3
- 【下载频次】61