【摘要】 超导材料的合成机理研究极富挑战性,已引起人们的极大兴趣,铜氧桥联配合物在超导方面的研究很有价值。首先用计算机模拟出合理的分子模型,经筛选,确定邻苯二酚、对苯二酚的铜氧桥联配合物,设计出合理的路线,合成并利用元素分析,红外光谱等表征了该配合物。更多还原

【Abstract】 The syntheses of superconductive meterials and the studies of their mechanism have challenged much attention. The studies of the copper complexes bridged by oxygen on superconductivity are very valuable. Many molecular models have been simulated by computer and the complexes of Cu ( II ) with hydroquinone and resorcin have been sifted, synthesized and characterized by element analysis and IR spectra.更多还原