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富马酸二甲酯的合成
Synthesis of Dimethyl Fumarate
【摘要】 马来酸酐与甲醇在强酸性阳离子交换树脂催化作用下发生酯化反应,所得产物马来酸二甲酯再在溴存在下经光照即可异构化成富马酸二甲酯.该法具有操作简便、反应条件温和、产物纯度高等优点.
【Abstract】 By strongly acidic cationic exchange resin as catalyst, esterification reaction take place between maleic anhydride and methanol.Then the intermediate,dimethyl maleate is isomerized into dimethyl fumarate under light and in the presence of bromine. The method has advantage of simple operation, mild reaction conditions and high purity of the product.
【关键词】 离子交换树脂;
催化剂;
酯化;
异构化;
富马酸二甲酯;
【Key words】 ion exchange resin; catalyst; esterification; isomerization; dimethyl fumarate;
【Key words】 ion exchange resin; catalyst; esterification; isomerization; dimethyl fumarate;
- 【文献出处】 湖南师范大学自然科学学报 ,JOURNAL OF NATURNAL SCIENCE OF HUNAN NORMAL UNIVERSITY , 编辑部邮箱 ,1997年03期
- 【分类号】O623.6
- 【被引频次】8
- 【下载频次】131