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重金属离子在腐植酸上吸附的研究
Adsorption of Heavy Metal Ions on Humic Acid
【摘要】 对4种代表性重金属离子在腐植酸上吸附、pH对竞争吸附的影响及其吸附机理进行了研究。结果表明,Cu2+、Pb2+、Zn2+的吸附等温线为F型,而Cd2+等温线为L型;2.5<pH<3.5时,竞争吸咐次序为Cu2+>Pb2+>Cd2+>Zn2+;pH>5.0时,Cd2+>Cu2+>Zn2+>Pb2+;Cu2+在腐植酸上的吸附主要是以与腐植酸形成配合物的方式相互结合。
【Abstract】 The adsorption characteristics of four typical heavy metal ions on humic acids was studied.The results showed that the isotherms were of F type Cu2+, Pb2+, Zn2+, L type for Cd2+. The competitive adsorption series are Cu2+ >Pb2+ >Cd2+ >Zn2+at 2. 5<pH< 3. 5, Cd2+ >Cu2+ >Zn2+>Pb2+ at pH>5. 0 and the mechanism of Cu2+ adsorbed by humic acids was to form compound.
【基金】 国家自然科学基金
- 【文献出处】 环境污染与防治 ,ENVIRONMENTAL POLLUTION & CONTROL , 编辑部邮箱 ,1997年01期
- 【分类号】X13
- 【被引频次】123
- 【下载频次】1037