节点文献
羟基磷酸钙 ESR 信号热衰退中的二级动力学过程
Second-order decay kinetics for the g=2.0018 ESR line of hydroxyapatite
【摘要】 人工合成羟基磷酸钙和牙珐琅化石的等温退火实验表明,它们的ESR信号的热衰退系一级和二级动力学过程的混合效应。二级衰退常数强烈依赖于温度,粗测其值在280℃时为10-19g/s量级。二级过程的存在对ESR法测早期古人类遗址动物牙化石年龄的影响需进一步研究。
【Abstract】 The isothermal annealing experiments on synthetic hydroxyapatite and fossil tooth enamel samples show that the decay of its g=2.0018 line obeys the mixed first- and second-order annealing kinetics. The 2nd-order decay constant depends strongly on temperature and is roughly estimated to be about 10 -19 g/s for hydroxyapatite at 280℃. The effect of the 2nd-order annealing kinetics on ESR dating of ancient (early Pleistocene) fossil tooth enamel samples should be further studied.
【关键词】 电子自旋共振测年;
羟基磷酸钙;
二级热衰退动力学过程;
【Key words】 ESR dating; Hydroxyapatite; Second-order decay kinetics;
【Key words】 ESR dating; Hydroxyapatite; Second-order decay kinetics;
【基金】 国家自然科学基金
- 【文献出处】 核技术 ,NUCLEAR TECHNIQUES , 编辑部邮箱 ,1997年08期
- 【分类号】O571.3
- 【被引频次】3
- 【下载频次】41