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CTMAB-膨润土吸附水中有机物的性能及应用

THE PROPERTIES FOR CTMAB-BENTONITE TO ADSORB SOME ORGANIC COMPOUNDS AND APPLICATION IN WASTEWATER TREATMENT

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【作者】 朱利中李益民陈曙光刘文涵包丽君

【Author】 Zhu Lizhong Li Yimin Chen Shuguang(Department of Environmental Sceiences, Hangzhou University, Hangzhou, 310028)Liu Wenhan Bao Lijun(College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014)

【机构】 杭州大学环境科学系浙江工业大学化工学院浙江工业大学化工学院 杭州310028杭州310028绍兴文理学院化学系杭州310028杭州310014

【摘要】 本文用溴化十六烷基三甲铵(CTMAB)-改性膨润土,研究了CTMAB-膨润土吸附水中α-萘胺、β-萘胺、α-萘酚、硝基苯和苯胺的性能和适宜条件.结果表明,CTMAB-膨润土对水中有机物的吸附能力与CTMAB在膨润土上的实际交换量有关,也与作用方式和有机物辛醇-水分配系数有关.CTMAB-膨润土对五种有机物的去除率顺序为:α-萘胺、β-萘胺、α-萘酚>硝基苯>苯胺.

【Abstract】 The CTMAB-bentonites were synthesized by cation exchange reaction between cetyltrimethylammonium bromide (CTMAB) and bentonite. The optimum conditions using CTMAB-bentonites for adsorption of α-naphthylamine, β-naphthylamine, a-naph-thol, nitrobenzene and aniline in water were investigated in detail. The removal order for organic compounds in water are as follows: α-naphthylamine, β-naphthylamine, α-naphthol>nitrobenzene>aniline. The structure of CTMAB-bentonite and its adsorption mechanism were studied by X-ray diffraction and octanol-water partition coefficient (Kow) of organics.

【基金】 浙江省自然科学基金及省教委资助课题
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,1997年03期
  • 【分类号】O647.3
  • 【被引频次】86
  • 【下载频次】356
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