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P350萃淋树脂分离微量镓的性能研究
Study on Properties of Separating Trace Ga with P 350 Extraction Eluation Resin
【摘要】 本文利用微色谱柱研究了甲基膦酸二甲庚酯(P350)对Ga的吸附性能,在4mol/lHCl介质中镓的上柱率为100%,吸附在柱上的镓可用1mlH2O.1mol/LHCl或1.5mol/LHBr洗脱,在3mm色谱柱上的吸附容量为18.2mg/g干树脂。同时采用静态法研究了酸度,时间、温度、浓度等因素对吸附的影响
【Abstract】 The separation and determination of trace Gallium with P 350 extraction-eluation resin is studied .The Gallium is quantitatively adsorbed on chromatographic micro column with 3 mm form 4 mol/L HCl or 6 mol/L HBr solution and eluted with 1 ml H 2O 1 mol/L HCl or 1.5 mol/L HBr The dynamic and static adsorption capacity of resin to Gallium is 18.2 mg/g and 12.4 mg/g dry resin respectively .It is studied that acidity time rate and constant make effect absorption reaction by using static state method .
【关键词】 微色谱柱;
镓;
P350;
吸附性能;
【Key words】 Chromatographic micro column; Gallium; P 350; Absroption property;
【Key words】 Chromatographic micro column; Gallium; P 350; Absroption property;
- 【文献出处】 华东地质学院学报 ,JOURNAL OF EAST CHINA GEOLOGICAL INSTITUTE , 编辑部邮箱 ,1997年02期
- 【分类号】O656.21
- 【被引频次】9
- 【下载频次】104