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盐酸三甲胺三氧化铬/硅胶对醇类化合物的氧化研究
Oxidation of Alcohols with Trimethylammonium Chlorochromate/Silica Gel
【摘要】 报道了盐酸三甲胺三氧化铬/硅胶对醇类化合物的氧化反应。盐酸三甲胺三氧化铬/硅胶可在多种介质中氧化伯醇和仲醇成为相应的醛或酮,反应条件温和、操作简单、收率高。
【Abstract】 This paper reported the oxidation of alcohols with trimethylammonium chlorochromate/silica gel. Primary and secondary alcohols were oxidized to corresponding aldehydes and ketones with high yields. The oxidation conditions were mild and the products of oxidation were easily separated. The oxidation of alcohols with this reagent can be carried out easily in some of selected solvents.
【关键词】 盐酸三甲胺三氧化铬/硅胶;
醇;
氧化;
【Key words】 Trimethylammonium chlorochromate/silica gel; Alcohols; Oxidation.;
【Key words】 Trimethylammonium chlorochromate/silica gel; Alcohols; Oxidation.;
【基金】 国家及河南省自然科学基金
- 【文献出处】 合成化学 ,CHINESE JOURNAL OF SYNTHETIC CHEMISTRY , 编辑部邮箱 ,1997年03期
- 【分类号】O623
- 【被引频次】6
- 【下载频次】129