节点文献
(R)-N-乙酰四氢噻唑-2-硫酮-4-羧酸与醇的反应
Reaction of (R) Acetylthiazolidine 2 thione 4 carboxylic Acid with Alcohols
【摘要】 (R)-N-乙酰四氢噻唑-2-硫酮-4-羧酸与醇反应,在SOCl2存在下得到乙酸酯及四氢噻唑-2-硫酮-4-羧酸酯;在碳酸钾存在下得到乙酸酯及四氢噻唑-2-硫酮-4-羧酸;在二环己基碳二亚胺(DCC)存在下得到缩水产物N-乙酰四氢噻唑-2-硫酮-4-羧酸酯。
【Abstract】 The N acetylthiazolidine 2 thione 4 carboxylic acid (2) was obtained through the reaction of acetic anhydride with (R) thiazolidine 2 thione 4 carboxylic acid. Product 2 reacted with benzyl alcohol to produce the corresponding acetic ester and (R) thiazolidine 2 thione 4 carboxylic acid in the presence of K 2CO 3. When the 2 reacted with alcohols in the presence of SOCl 2 the acetic esters and (R) thiazolidine 2 thione 4 carboxylic esters were formed. But the 2 reacted with alcohol in the presence of DCC the (R) N acetylthiazolidine 2 thione 4 carboxylic ester was prepared.
【Key words】 R) N acetylthiazolidine 2 thione 4 carboxylic acid; (R) N acetylthiazolidine 2 thione 4 carboxylic acid ester; (R) Thiazolidine 2 thione 4 carboxylic acid.;
- 【文献出处】 合成化学 ,CHINESE JOURNAL OF SYNTHETIC CHEMISTRY , 编辑部邮箱 ,1997年03期
- 【分类号】O623.624
- 【被引频次】2
- 【下载频次】86