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云母微晶玻璃析晶动力学的研究
STUDY ON THE CRYSTALLIZATION KINETICS OF MICA GLASSCERAMICS
【摘要】 采用差热分析的方法,对TiO2作为晶核剂的氟金云母微晶玻璃的析晶动力学参数进行了测定。结果表明:TiO2使原始玻璃在晶化过程中产生了先析相钛酸镁,降低了氟金云母相的析晶活化能;氟金云母晶体以二维片层状方式生长,其生长过程受界面过程控制。
【Abstract】 Crystallization kinetics parameters of micacontaining glass ceramics with TiO 2 as a nucleation agent were measured by DTA.The results indicate that the nucleation and crystal growth of mica phase are enhanced by the addition of TiO 2,which decreases the crystallization activation energy of mica.The growth of mica crystals is controlled by interface process,thus lamella mica crystals are formed.
- 【文献出处】 硅酸盐学报 ,JOURNAL OF THE CHINESE CERAMIC SOCIETY , 编辑部邮箱 ,1997年05期
- 【分类号】TQ171.733
- 【被引频次】43
- 【下载频次】306